Solute-water interactions in the aquation of Isonicotinohydrazide and nicotinic acid complexes of pentacyanoferrate(n) at various pH

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cnea.tipodocumentoARTÍCULO CIENTÍFICO
dc.contributor.authorBlesa, Miguel A.
dc.contributor.authorFunai, Irene A.
dc.contributor.authorMorando, Pedro J.
dc.contributor.authorOlabe, José A.
dc.date.accessioned2024-09-25T16:14:01Z
dc.date.available2024-09-25T16:14:01Z
dc.date.issued1977
dc.description.abstractChanges in the rate constants and activation parameters of the title reactions, as the state of protonation of the outgoing ligand and cyanides changes, seem to reflect solely changes due to the different charge type, i.e. the different contribution from water structuring around the activated complex. Rate constants for the title and related reactions are remarkably insensitive to changes in Fe—N bonding.
dc.description.institutionalaffiliationFil.: Blesa, Miguel A. Comisión Nacional de Energía Atómica; Argentina
dc.description.institutionalaffiliationFunai, Irene A. Universidad de Buenos Aires; Argentina
dc.description.institutionalaffiliationMorando, Pedro J. Comisión Nacional de Energía Atómica; Argentina
dc.description.institutionalaffiliationexternalFil.: Olabe, José A. Universidad de Luján; Argentina
dc.format.extent2092-2095 p.
dc.format.extentapplication/pdf
dc.identifier.cnea03.77.04
dc.identifier.doihttps://doi.org/10.1039/DT9770002092
dc.identifier.urihttps://nuclea.cnea.gob.ar/handle/20.500.12553/5752
dc.language.ISO639-3eng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofJournal Chemistry Society, Dalton Transaction N°21 (1977)
dc.rights.accesslevelinfo:eu-repo/semantics/openAccess
dc.rights.licenseCreative Commons Atribución-NoComercial-CompartirIgual 4.0 Internacional
dc.rights.urihttps://creativecommons.org/licenses/by-nc-sa/4.0/
dc.subject.inisREACCIONES QUIMICAS
dc.subject.inisCIANUROS
dc.subject.inisACTIVACION QUIMICA
dc.subject.inisACIDO NICOTINICO
dc.subject.inisCOORDINANTES
dc.subject.inisSOLUCIONES DE AGUA
dc.subject.inisINDICE DE ACIDEZ
dc.subject.inisCHEMICAL REACTIONS
dc.subject.inisCYANIDES
dc.subject.inisCHEMICAL ACTIVATION
dc.subject.inisNICOTINIC ACID
dc.subject.inisLIGANDS
dc.subject.inisWATER SOLUTIONS
dc.subject.inisPH VALUE
dc.titleSolute-water interactions in the aquation of Isonicotinohydrazide and nicotinic acid complexes of pentacyanoferrate(n) at various pH
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:ar-repo/semantics/artículo
dc.type.versioninfo:eu-repo/semantics/publishedVersion

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