Neutron diffraction studies of tetrachloride liquids. IV: The molecular beat effect for TiCl4; SiCl4 and Tic4; SnCl4 mixtures.

Abstract

Neutron diffraction measurements of mixtures of T iC l4/SiCl4 and TiC l4/SnC l4 liquids have been made using the total scattering spectrometer of the Harwell Electron Linac. The high 0 -value (5-20 Á-1) data exhibit a beat effect and have been analysed in terms of summed molecular form factors. The bond-length parameters are found to be in good agreement with other values and confirm the treatment adopted in the analysis of the data for the pure liquids.