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EPR of Pentavalent Molybdenum in Liquid Solutions

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cnea.tipodocumentoARTÍCULO CIENTÍFICO
dc.contributor.authorAbraham, M. M.
dc.contributor.authorAbriata, José Pablo
dc.contributor.authorFoglio, M. E.
dc.contributor.authorPasquini, E.
dc.date.accessioned2024-09-25T16:10:00Z
dc.date.available2024-09-25T16:10:00Z
dc.date.issued1966
dc.description.abstractThe paramagnetic resonance of Mo5+ in liquid solution with two different (chloride and thiocyanate)complexes has been observed. In each case, a hyperfine interaction due to the odd isotopes of molybdenum was observed, in addition to the contribution of the zero-spin isotopes which yield a single line at the center of the spectrum. Upon freezing the solutions, the resonance spectra may be described by spin Hamiltonians possessing axial symmetry. The averages of the g tensor and the hyperfine tensor agree very well with the measured values obtained with the liquid solutions.
dc.description.institutionalaffiliationFil: Abraham, M. M. Comisión Nacional de Energía Atómica; Argentina
dc.description.institutionalaffiliationAbriata, José Pablo Comisión Nacional de Energía Atómica; Argentina
dc.description.institutionalaffiliationFoglio, M. E. Comisión Nacional de Energía Atómica; Argentina
dc.description.institutionalaffiliationPasquini, E. Comisión Nacional de Energía Atómica; Argentina
dc.description.institutionalaffiliationexternalFil: Abraham, M. M. Laboratorio Nacional Oak Ridge, Oak Ridge, Tennessee, Estados Unidos
dc.format.extent2069-2070 p.
dc.format.extentapplication/pdf
dc.identifier.cnea03.66.01
dc.identifier.doihttps://doi.org/10.1063/1.1727892
dc.identifier.urihttps://nuclea.cnea.gob.ar/handle/20.500.12553/5691
dc.language.ISO639-3eng
dc.publisherElsevier BV
dc.relation.ispartofJournal of Chemical Physics V. 45 (6) 1966
dc.rights.accesslevelinfo:eu-repo/semantics/openAccess
dc.rights.licensecreative Commons Atribución-NoComercial-CompartirIgual 4.0 Internacional
dc.rights.urihttps://creativecommons.org/licenses/by-nc-sa/4.0/
dc.subject.inisRESONANCIA PARAMAGNETICA (NUCLEAR)
dc.subject.inisESTRUCTURA HIPERFINA
dc.subject.inisCLORUROS
dc.subject.inisTIOCIANATOS
dc.subject.inisHAMILTONIANOS
dc.subject.inisSIMETRIA AXIAL
dc.subject.inisPARAMAGNETIC RESONANCE (NUCLEAR)
dc.subject.inisHYPERFINE STRUCTURE
dc.subject.inisCHLORIDES
dc.subject.inisTHIOCYANATES
dc.subject.inisHAMILTONIANS
dc.subject.inisAXIAL SYMMETRY
dc.titleEPR of Pentavalent Molybdenum in Liquid Solutions
dc.typeARTÍCULO
dc.type.versioninfo:eu-repo/semantics/publishedVersion
dspace.entity.typePublication

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