2.Synthesis, crystal structure and magnetic properties of the mixed-ligand complex [Gd(F3CCO2)3(phen)2(H2O)]
| cnea.tipodocumento | ARTÍCULO CIENTÍFICO | |
| dc.contributor.author | Rizzi, Alberto Claudio | |
| dc.contributor.author | Baggio, Ricardo Fortunato | |
| dc.contributor.author | Calvo, Rafael | |
| dc.contributor.author | Garland, Marías | |
| dc.contributor.author | Peña, Octavio | |
| dc.contributor.author | Perec, Mireille | |
| dc.date.accessioned | 2025-12-11T23:26:47Z | |
| dc.date.available | 2025-12-11T23:26:47Z | |
| dc.date.issued | 2001-01 | |
| dc.description.abstract | The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2(H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd−Gd separation of 7.16(1) Å. Magnetic susceptibility and EPR measurements showed weak magnetic exchange coupling of the 3D type. | |
| dc.description.institutionalaffiliation | Fil: Rizzi, Alberto Claudio. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina | |
| dc.description.institutionalaffiliation | Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina | |
| dc.description.institutionalaffiliation | Fil: Calvo, Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina | |
| dc.description.institutionalaffiliation | Fil: Garland, Marías. Universidad de Chile; Chile | |
| dc.description.institutionalaffiliation | Fil: Peña, Octavio. Universite de Rennes I; Francia | |
| dc.description.institutionalaffiliation | Fil: Perec, Mireille. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina | |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.uri | https://nuclea.cnea.gob.ar/handle/20.500.12553/8271 | |
| dc.publisher | American Chemical Society | |
| dc.relation | info:eu-repo/semantics/reference/hdl/11336/27819 | |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/ic001243v | |
| dc.rights.license | info:eu-repo/semantics/openAccess | |
| dc.rights.license | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
| dc.subject | Epr | |
| dc.subject | Gd(Iii) | |
| dc.subject | Complexes | |
| dc.subject | Otras Ciencias Químicas | |
| dc.subject | Ciencias Químicas | |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | |
| dc.title | 2.Synthesis, crystal structure and magnetic properties of the mixed-ligand complex [Gd(F3CCO2)3(phen)2(H2O)] | |
| dc.type | ARTÍCULO | |
| dc.type.version | Versión publicada |
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